Introduction to Third Row Elements

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Reasons for The Study of The Third Row Elements:

  • The elements are arranged in the order of increasing atomic numbers, in such a way that elements with similar properties fall in the same vertical column of the periodic table. There are eighteen vertical columns known as groups and seven horizontal rows are known as periods.
  • All these elements have vacant 3d orbitals. These elements are capable of transferring their valence electrons to these vacant d orbitals. Thus they are capable of expanding their octet which is not possible in the second-row elements.

Third Row Elements:

  • A group of eight elements namely, sodium (Na), magnesium (Mg), aluminium (Al), silicon(Si), phosphorous (P), sulphur (S), chlorine(Cl) and argon (Ar) belongs to the third period of the periodic table are called as third row elements.
  • The properties of each element are character­istics of the group to which they belong.  Each one of these elements can, therefore, be considered as the representative of the whole group to which it belongs.  Hence the third-row elements are known as typical or representative elements.
  • The properties of these elements gradually change from metallic or basic to non-metallic or acidic character across the third period. Sodium, magnesium and aluminium are metals.  They have a metallic lustre, can conduct heat and electricity.  They are malleable and ductile.  Sodium is very soft metal. Silicon is hard solid and is metalloid. Phosphorous is yellow waxy solid.  It is non-metal.  Sulphur is yellow coloured solid.  It is a non-metal.  Chlorine and argon are gases at room temperature.  They are non-metals.

Position Of The Third Row Elements In The Periodic table:

Third Row Elements 01

  • In the modern periodic table, third row elements have been placed in 1, 2, 13, 14, 15, 16, 17 and 18 groups. Except for Sodium and Argon, the third-row elements are the second member of their group. Sodium and Argon  are the third members of their groups 1 and 18 respectively
  • For sodium and magnesium, the last electron to be configured enter into ‘s’ orbitals. Hence sodium and magnesium are s block elements. For all the other third row elements the last electron to be configured enter into ‘ ‘p’ orbitals hence they are p block elements.
  • There are three orbits and valence electrons are present in third main energy level.

Electronic Configuration of Third Row Elements:

  • Electronic configuration of third row elements of the third row is as fol­lows

Third Row Elements 02

  • It can be seen that Sodium ( Z = 11)  has a single electron in its 3 s valency orbital. With the increase in atomic number, in magnesium, aluminium, silicon, phosphorous and chlorine, the electrons successively occupy 3s and 3p valence orbitals until another closed shell configu­ration 1s22s2 2p63s23p6 is reached at argon (Z = 18).

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